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Tantalum(IV) sulfide
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Tantalum(IV) sulfide : ウィキペディア英語版
Tantalum(IV) sulfide

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Tantalum(IV) sulfide is the inorganic compound with the formula TaS2. It is a layered compound with three-coordinate sulfide centres and trigonal prismatic metal centres. It is structurally similar to the more famous material molybdenum disulfide, MoS2. TaS2 is a semiconductor with d1 electron configuration. Although an obscure material otherwise, TaS2 has been the subject of many studies because it is a versatile host for intercalation of electron donors.〔J. F. Revelli, "Tantalum Disulfide (TaS2) and Its Intercalation Compounds" ''Inorganic Syntheses'' 1995, volume 30, pp. 155. 〕
==Preparation==
TaS2 is prepared by the high temperature reaction of powdered tantalum and sulfur. It is purified and crystallized by chemical vapor transport using iodine as the transporting agent:
:TaS2 + 2 I2 \overrightarrow TaI4 + 2 S

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